📘 Understanding Henry’s Law Constant (KH) and Its Applications

 Here’s a CBSE Class 12 board exam–oriented and classroom-friendly explanation of the above content from the NCERT Henry’s Law section, including the meaning of Henry’s constant (KH), the graph, and the effect of temperature — all simplified for better understanding:


📘 Understanding Henry’s Law Constant (KH) and Its Applications


🔬 What is KH?

  • KH is the Henry’s Law constant.

  • It tells us how easily a gas dissolves in a liquid under pressure.

📖 From Henry’s Law:

p=KHxp = K_H \cdot x

Where:

  • p = partial pressure of the gas

  • x = mole fraction (solubility) of the gas

  • KH = constant (depends on gas and temperature)


📈 Graph Between p and x (Henry’s Law – Fig. 2.2)

  • If you plot:

    • Y-axis = partial pressure of gas (p)

    • X-axis = mole fraction (x)

  • You get a straight line, with slope = KH

📌 Higher slope = less solubility, because KH is higher.


📌 Interpretation of KH:

Higher the value of KH, the lower the solubility of the gas at a given pressure.

✅ So, gases with low KH values dissolve more easily.
❌ Gases with high KH values are less soluble.


🧪 Examples from Table 2.2:

Gas Temp (K) KH (kbar) Solubility Trend
CO₂ 298 1.67 Very high solubility
O₂ 293 34.86 Moderate
N₂ 293 76.48 Low
He 293 144.97 Very low
Methane 298 0.413 High solubility

🌡️ Effect of Temperature on KH:

  • KH increases with temperature

  • So, gas solubility decreases as temperature increases

  • That’s why cold water holds more dissolved oxygen than warm water


🐟 Real-Life Example:

Aquatic animals live better in cold water because cold water dissolves more oxygen (lower KH).


📝 CBSE Exam Tips:

  • Always mention that KH depends on the nature of gas and temperature

  • State clearly:

    Higher KH ⇒ lower solubility
    Higher temperature ⇒ higher KH ⇒ lower solubility


Would you like me to prepare a clean classroom chart with this KH table, graph, and summary points for display or slides?

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